| Introduction | The Model (VSEPR) | Examples |
The electrons around the atoms in a molecule repel each other. They move to be as far apart as possible while still maintaining the bonding within the molecule. The procedure for using the model is as follows:
1) Determine the correct Lewis
structure for the molecule.
If it is a diatomic (has only two atoms) it is linear and falls into
the AX category. If it has 3 or
more atoms continue with step 2.
2) Count the number of electron groups around the central atom. A group of electrons is a bond, a nonbonding electron pair, or occasionally an unpaired nonbonding electron. Each triple or double bond counts as only one group for the purposes of this model.
3) Based on this number of groups around the central atom the
molecule falls into one of six basic
categories. Within each category there are a number of different
names for the shapes depending upon the number of atoms and nonbonding
groups around the central atom.
| Number of Groups around central atom | Shape when all groups are bonded atoms Electron geometry and molecular geometry are the same (click
links to see examples you can manipulate)
|
Sub-Shapes (molecular geometry) A = central atom, X = atom attached to central atom, E = nonbonding electron group on central atom (click links to see examples you can manipulate) |
| Diatomic (any number of groups) |
Linear Diatomic
|
Linear (AX) |
| 2 |
Linear
Triatomic![]() |
Linear (AX2) |
| 3 |
Trigonal
Planar![]() |
Trigonal Planar (AX3)
Bent (AX2E) |
| 4 |
Tetrahedral![]() |
|
| 5 |
Trigonal
Bipyramidal![]() |
|
| 6 | Octahedral![]() |