AX5, AX4E, AX3E2 and AX2E3 Configurations

Molecules in this category may have three, four, five or six atoms.  The configuration is specified as AX5 for the case with six total atoms and AX4E for the case with five atoms, AX3E2 for the case with four and AX2E3 for the case with three.  Remeber the "E" represents electron groups that are not involved in bonding, the "X" atoms around the central atom and the "A" is the central atom.  Molecules of the type AX5 are trigonal bipyramidal, molecules of the type AX4E  are seesaw, molecules of the type AX3E2 are T-shaped, and molecules of the type AX2E3 are linear.
Example AX5 Molecules (Trigonal Bipyramidal)
PCl5 Rotatable 3-D image in browser
RasMol file
PF5 Rotatable 3-D image in browser
RasMol file

Example AX4E Molecules  (Seesaw)

SF4  Rotatable 3-D image in browser
RasMol file
ClF4+
ClF4+ Lewis Structure
Rotatable 3-D image in browser
RasMol file

Example AX3E2 (T-shaped)

ClF3 Rotatable 3-D image in browser
RasMol file

Example AX2E3 (Linear)

XeF2 Rotatable 3-D image in browser
RasMol file


Last updated: December 24, 2006
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