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Vibration Frequencies for Cl₂O₂

The frequency of vibrations for the Cl₂O₂ molecule were calculated from the ab initio DZV basis set. These frequencies correspond to the frequencies at which an IR peak should be observed. The calculated frequencies of vibration and experimentally determined frequencies are listed in Table 1 along with descriptions of the vibration.

Table 1: Vibration frequencies for Cl₂O₂.

Experimental Frequency (cm^-1)³	Calculated Frequency (cm^-1)	Description of Vibration
Not Listed		Scissoring
418.5 (weak)		Deformation
Not Listed		Rocking
543.0 (medium)		Cl-O Symmetric Stretch
647.7 (v. strong)		Cl-O Asymmetric Stretch
754.0 (medium)		O-O Stretch

Experimental IR frequencies and assignments can be found at this National Institute of Standards and Technology (NIST) Chemistry WebBook Page.

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Vibration Frequencies for Cl2O2

Vibration Frequencies for Cl₂O₂